Search results for "diffusion rate"

showing 2 items of 2 documents

On the blue phase structure of hydrogen-bonded liquid crystals via 19F NMR

2018

Abstract 19 F NMR spectra are simulated for blue phase I of FPHG( St 1.5 ∗ Ap 1.5 ) based on a model of a double-twisted substructure inside cylinders that form a body-centred cubic lattice. A kinetic matrix is included to describe jump processes over quarter pitch lengths. Though the lines in the NMR spectra are broad and featureless, changes in the widths and positions with temperature are well described by the blue phase model structure. The spectra in the chiral nematic N∗ phase are also simulated. Dynamics in the BP I are found to be slower than in the N∗ phase.

Materials scienceHydrogenSpectral simulationChemieGeneral Physics and Astronomychemistry.chemical_elementBlue phase IDouble-twisted substructure02 engineering and technologyFluorine-19 NMR010402 general chemistryKinetic energy01 natural sciencesMolecular physicsSpectral lineDiffusion rateLiquid crystalLattice (order)Physical and Theoretical Chemistry021001 nanoscience & nanotechnologyFluorine NMR0104 chemical sciencesNMR spectra databasechemistrySubstructureSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyChiral nematic
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A study of VUV emission and the extracted electron-ion ratio in hydrogen and deuterium plasmas of a filament-driven H−/D− ion source

2019

Vacuum ultraviolet (VUV) emission diagnostics for studying differences of electron impact processes in hydrogen and deuterium plasmas are presented. The method is applied to study a filament driven multicusp arc discharge negative ion source by comparing the VUV-emission intensities of different emission bands and extracted currents of H−/D− ions and electrons. It was found that the ratio of coextracted electrons to extracted ions is four times higher for deuterium than for hydrogen. No significant differences of the VUV-spectra or volumetric rates of ionization, excitation, production of high vibrational states, and dissociation were found between the plasmas of the two isotopes. The volum…

diffusion rateisotoopitplasma diagnosticselectron impact ionizationplasmafysiikkavacuum ultraviolet radiationelectron impact emission spectroscopyion sourcesPhysics::Plasma Physicselectric dischargesPhysics::Atomic and Molecular Clustersisotopesvibrational statesplasma spectroscopy
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